The final stages of the two syntheses are concerned with the functionalization of the alkene and the allylic alcohol, respectively, and the introduction of the ester side chains. A salient feature ...

In recent research 4 we have observed a case of true electromerism in a pair of organic radical cations containing two allylic moieties. The two electromers distinguish themselves by the nature of ...

A more reasonable scenario postulated by Pryor and Porter, involves an Epoxy Hydroperoxide Fragmentation (2). The key cyclization of an allylic alkoxyl radical to a carbon-centered allylic radical had ...

During 1977-78, the final year of my PRF grant support, I initiated a spin-off investigation of [1,3]-allylic rearrangements. We completed the first systematic study of thermal [1,3]-allylic ...

Examples of compounds that may cause sensitization in some individuals are diazomethane, various isocyanates, formaldehyde, and benzylic and allylic halides. Avoid skin contact with chemicals ...

Then, he will discuss the design of cyclic allylic sulfones which can undergo a radical cascade-triggered ring-opening polymerization, making them possess broad reactivities to vinyl monomers and ...